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Page 1 of 5 Coin/Button Lithium Manganese Dioxide Batteries March 2016 PRODUCT SAFETY DATA SHEET PRODUCT NAME: Energizer Battery Type No.: Volts: 3.0 TRADE NAMES: Coin/Button Lithium Manganese Dioxide Batteries Approximate Weight: 0.6 7.0 g CHEMICAL SYSTEM: Lithium Manganese Dioxide Designed for Recharge: No Document Number: 12005-A Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. Batteries are articles as defined under the GHS and exempt from GHS classification criteria (Section 1.3.2.1.1 of the GHS). The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC. MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT. SECTION 1- MANUFACTURER INFORMATION Manufactured for Energizer Battery Manufacturing, Inc. Telephone Number for Information: 25225 Detroit Rd. 800-383-7323 (USA / CANADA) Westlake, OH 44145 Date Prepared: March 2016 SECTION 2 HAZARDS IDENTIFICATION GHS classification: N/A Signal Word: N/A Hazard Classification: N/A Under normal conditions of use, the battery is hermetically sealed. Ingestion: Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the esophagus. Immediately see doctor have doctor phone (202) 625-3333. Do not induce vomiting or give food or drink. Inhalation: Contents of an open battery can cause respiratory irritation. Skin Contact: Contents of an open battery can cause skin irritation. Eye Contact: Contents of an open battery can cause severe irritation. SECTION 3 - INGREDIENTS IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt. 3 3 Carbon Black 3.5 mg/m TWA 3.5 mg/m TWA 0-1 (CAS 1333-86-4) 1,2-Dimethoxyethane None established None established 0-6 (CAS 110-71-4) 1,3-Dioxolane None established None established 0-8 (CAS 646-06-0) 3 3 Graphite 15 mg/m TWA (total dust) 2 mg/m TWA (respirable fraction) 0-3 3 (CAS 7782-42-5) 5 mg/m TWA (respirable fraction) Lithium or Lithium Alloy None established None established 1-6 (CAS 7439-93-2) 2016 Energizer Page 2 of 5 Coin/Button Lithium Manganese Dioxide Batteries March 2016 Lithium Perchlorate None established None established 0-3 (CAS 7791-03-9) Lithium Trifluoromethanesulfonate None established None established 0-3 (CAS 33454-82-9) Lithium Trifluoromethanesulfonimide None established None established 0-3 (CAS 90076-65-6) 3 3 Manganese Dioxide 5 mg/m Ceiling (as Mn) 0.2 mg/m TWA (as Mn) 12-42 (CAS 1313-13-9) Propylene Carbonate None established None established 0-8 (CAS 108-32-7) Non-Hazardous Components: Steel None established None established 20 (iron CAS 65997-19-5) Plastic and Other None established None established Balance SECTION 4 FIRST AID MEASURES Ingestion: Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the esophagus. Immediately see doctor have doctor phone (202) 625-3333. Do not induce vomiting or give food or drink. Inhalation: Provide fresh air and seek medical attention. Skin Contact: Remove contaminated clothing and wash skin with soap and water. Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention. Note: Carbon black is listed as a possible carcinogen by International Agency for Research on Cancer (IARC). SECTION 5- FIRE FIGHTING MEASURES In case of fire where lithium batteries are present, flood area with water or smother with a Class D fire extinguishant appropriate for lithium metal, such as Lith-X. Water may not extinguish burning batteries but will cool the adjacent batteries and control the spread of fire. Burning batteries will burn themselves out. Virtually all fires involving lithium batteries can be controlled by flooding with water. However, the contents of the battery will react with water and form hydrogen gas. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended. A smothering agent will extinguish burning lithium batteries. Emergency Responders should wear self-contained breathing apparatus. Burning lithium manganese dioxide batteries produce toxic and corrosive lithium hydroxide fumes. SECTION 6 - ACCIDENTAL RELEASE MEASURES To cleanup leaking batteries: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. Respiratory Protection: Avoid exposure to electrolyte fumes from open or leaking batteries. Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container. SECTION 7 - HANDLING AND STORAGE Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. In locations that handle large quantities of lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles. Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery Manufacturing, Inc. representative for precautionary suggestions. Do not obstruct safety release vents on batteries. Encapsulation of batteries will not allow cell venting and can cause high pressure rupture. 2016 Energizer